Sascha Hintenlang

Implementing A New Comonomer into the High-Pressure Polymerization with Ethene


voorkant	achterkant

ISBN:

978-3-8191-0714-6

Reeks:

Darmstädter Schriftenreihe der Polymerisationstechnik
Uitgever: Prof. Dr. Markus Busch
Darmstadt

Volume:

Trefwoorden:

Hochdruck; Ethen; LDPE; Polymerisation; Comonomer; Scale-up

Soort publicatie:

Dissertatie

Taal:

Engels

Pagina's:

184 pagina's

Gewicht:

327 g

Formaat:

24 x 17 cm

Bindung:

Softcover

Prijs:

58,80 € / 73,60 SFr

Verschijningsdatum:

November 2026

Kopen:

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Samenvatting

In this work, the implementation of a new comonomer vinyl neodecanoate into the free radical high-pressure polymerization with ethene was investigated. The following four topics were of interest, always with a focus on having data and knowledge at process temperatures and pressures:

thermophysical properties (compressibility, density, thermal expansion coefficient, and the change in heat capacity with pressure) of the new comonomer at conditions close to the large-scale process conditions
phase behavior of the co- and terpolymerization system
process safety with the focus on the comonomer’s effect on inherent safety
copolymerization kinetics of vinyl neodecanoate and ethene with a focus on reactivity ratios and transfer to vinyl neodecanoate